# Posts Tagged water ice

## Recent Postings from water ice

### Pore evolution in interstellar ice analogues: simulating the effects of temperature increase

Context. The level of porosity of interstellar ices – largely comprised of amorphous solid water (ASW) – contains clues on the trapping capacity of other volatile species and determines the surface accessibility that is needed for solid state reactions to take place. Aims. Our goal is to simulate the growth of amorphous water ice at low temperature (10 K) and to characterize the evolution of the porosity (and the specific surface area) as a function of temperature (from 10 to 120 K). Methods. Kinetic Monte Carlo simulations are used to mimic the formation and the thermal evolution of pores in amorphous water ice. We follow the accretion of gas-phase water molecules as well as their migration on surfaces with different grid sizes, both at the top growing layer and within the bulk. Results. We show that the porosity characteristics change substantially in water ice as the temperature increases. The total surface of the pores decreases strongly while the total volume decreases only slightly for higher temperatures. This will decrease the overall reaction efficiency, but in parallel, small pores connect and merge, allowing trapped molecules to meet and react within the pores network, providing a pathway to increase the reaction efficiency. We introduce pore coalescence as a new solid state process that may boost the solid state formation of new molecules in space and has not been considered so far.

### External Photoevaporation of the Solar Nebula: Jupiter's Noble Gas Enrichments

We present a model explaining elemental enrichments in Jupiter’s atmosphere, particularly the noble gases Ar, Kr, and Xe. While He, Ne and O are depleted, seven other elements show similar enrichments ($\sim$3 times solar, relative to H). Being volatile, Ar is difficult to fractionate from ${\rm H}_{2}$. We argue that external photoevaporation by far ultraviolet (FUV) radiation from nearby massive stars removed ${\rm H}_{2}$, He, and Ne from the solar nebula, but Ar and other species were retained because photoevaporation occurred at large heliocentric distances where temperatures were cold enough ($\lt 30$ K) to trap them in amorphous water ice. As the solar nebula lost H it became relatively and uniformly enriched in other species. Our model improves on the similar model of Guillot \& Hueso (2006). We recognize that cold temperatures alone do not trap volatiles; continuous water vapor production also is necessary. We demonstrate that FUV fluxes that photoevaporated the disk generated sufficient water vapor, in regions $\lt 30$ K, to trap gas-phase species in amorphous water ice, in solar proportions. We find more efficient chemical fractionation in the outer disk: whereas the model of Guillot \& Hueso (2006) predicts a factor of 3 enrichment when only $< 2\%$ of the disk mass remains, we find the same enrichments when 30\% of the disk mass remains. Finally, we predict the presence of $\sim 0.1 \, M_{\oplus}$ of water vapor in the outer solar nebula and in protoplanetary disks in H II regions.

### A Precise Water Abundance Measurement for the Hot Jupiter WASP-43b

The water abundance in a planetary atmosphere provides a key constraint on the planet’s primordial origins because water ice is expected to play an important role in the core accretion model of planet formation. However, the water content of the Solar System giant planets is not well known because water is sequestered in clouds deep in their atmospheres. By contrast, short-period exoplanets have such high temperatures that their atmospheres have water in the gas phase, making it possible to measure the water abundance for these objects. We present a precise determination of the water abundance in the atmosphere of the 2 $M_\mathrm{Jup}$ short-period exoplanet WASP-43b based on thermal emission and transmission spectroscopy measurements obtained with the Hubble Space Telescope. We find the water content is consistent with the value expected in a solar composition gas at planetary temperatures (0.4-3.5x solar at 1 $\sigma$ confidence). The metallicity of WASP-43b’s atmosphere suggested by this result extends the trend observed in the Solar System of lower metal enrichment for higher planet masses.

### The ancient heritage of water ice in the solar system

Identifying the source of Earth’s water is central to understanding the origins of life-fostering environments and to assessing the prevalence of such environments in space. Water throughout the solar system exhibits deuterium-to-hydrogen enrichments, a fossil relic of low-temperature, ion-derived chemistry within either (i) the parent molecular cloud or (ii) the solar nebula protoplanetary disk. Utilizing a comprehensive treatment of disk ionization, we find that ion-driven deuterium pathways are inefficient, curtailing the disk’s deuterated water formation and its viability as the sole source for the solar system’s water. This finding implies that if the solar system’s formation was typical, abundant interstellar ices are available to all nascent planetary systems.

### Water in Low-Mass Star-Forming Regions with Herschel: The Link Between Water Gas and Ice in Protostellar Envelopes

Aims: Our aim is to determine the critical parameters in water chemistry and the contribution of water to the oxygen budget by observing and modelling water gas and ice for a sample of eleven low-mass protostars, for which both forms of water have been observed. Methods: A simplified chemistry network, which is benchmarked against more sophisticated chemical networks, is developed that includes the necessary ingredients to determine the water vapour and ice abundance profiles in the cold, outer envelope in which the temperature increases towards the protostar. Comparing the results from this chemical network to observations of water emission lines and previously published water ice column densities, allows us to probe the influence of various agents (e.g., FUV field, initial abundances, timescales, and kinematics). Results: The observed water ice abundances with respect to hydrogen nuclei in our sample are 30-80ppm, and therefore contain only 10-30% of the volatile oxygen budget of 320ppm. The keys to reproduce this result are a low initial water ice abundance after the pre-collapse phase together with the fact that atomic oxygen cannot freeze-out and form water ice in regions with T(dust)>15 K. This requires short prestellar core lifetimes of less than about 0.1Myr. The water vapour profile is shaped through the interplay of FUV photodesorption, photodissociation, and freeze-out. The water vapour line profiles are an invaluable tracer for the FUV photon flux and envelope kinematics. Conclusions: The finding that only a fraction of the oxygen budget is locked in water ice can be explained either by a short pre-collapse time of less than 0.1 Myr at densities of n(H)~1e4 cm-3, or by some other process that resets the initial water ice abundance for the post-collapse phase. A key for the understanding of the water ice abundance is the binding energy of atomic oxygen on ice.

### Absorption of crystalline water ice in the far infrared at different temperatures [Replacement]

The optical properties of ice in the far infrared are important for models of protoplanetary and debris disks. In this report we derive a new set of data for the absorption (represented by the imaginary part of the refractive index $\kappa$) of crystalline water ice in this spectral range, including a detailed inspection of the temperature dependence, which had not been done in such detail before. We measured the transmission of three ice layers with different thicknesses at temperatures $\vartheta = 10…250$K and present data at wavelengths $\lambda=80…625$ microns. We found a change in the spectral dependence of $\kappa$ at a wavelength of $175 \pm 6$ microns. At shorter wavelengths, $\kappa$ exhibits a constant flat slope and no significant temperature dependence. Long-ward of that wavelength, the slope gets steeper and has a clear, approximately linear temperature dependence. This change in the behaviour is probably caused by a characteristic absorption band of water ice. The measured data were fitted by a power-law model that analytically describes the absorption behaviour at an arbitrary temperature. This model can readily be applied to any object of interest, for instance a protoplanetary or a debris disk. To illustrate how the model works, we simulated the spectral energy distribution (SED) of the resolved, large debris disk around the nearby solar-type star HD 207129. Replacing our ice model by another, commonly used data set for water ice results in a different SED slope at longer wavelengths. This leads to changes in the characteristic model parameters of the disk, such as the inferred particle size distribution, and affects the interpretation of the underlying collisional physics of the disk.

### Absorption of crystalline water ice in the far infrared at different temperatures

The optical properties of ice in the far infrared are important for models of protoplanetary and debris disks. In this report we derive a new set of data for the absorption (represented by the imaginary part of the refractive index $\kappa$) of crystalline water ice in this spectral range, including a detailed inspection of the temperature dependence, which had not been done in such detail before. We measured the transmission of three ice layers with different thickness at wavelengths $\lambda=45…1000$ microns at temperatures $\vartheta = 10…250$ K. We found a change in the spectral dependence of $\kappa$ at a wavelength of $175 \pm 6$ microns. At shorter wavelengths, $\kappa$ exhibits a constant flat slope and no significant temperature dependence. Long-ward of that wavelength, the slope gets steeper and has a clear, approximately linear temperature dependence. This change in the behaviour is probably caused by a characteristic absorption band of water ice. The measured data were fitted by a power-law model that analytically describes the absorption behaviour at an arbitrary temperature. This model can readily be applied to any object of interest, for instance a protoplanetary or a debris disk. To illustrate how the model works, we simulated the spectral energy distribution (SED) of the resolved, large debris disk around the nearby solar-type star HD 207129. Replacing our ice model by another, commonly used data set for water ice results in a different SED slope at longer wavelengths. This leads to changes in the characteristic model parameters of the disk, such as the inferred particle size distribution, and affects the interpretation of the underlying collisional physics of the disk.

### Lately Exposed Amorphous Water Ice on Comet 49P/Arend-Rigaux [Replacement]

Comet 49P/ Arend-Rigaux, thought to be a low activity comet since the 1980′s was found to be active in its recent apparitions. Recent analysis of the data obtained from Spitzer observation of the comet in 2006 compared with laboratory spectra has revealed amorphous water ice on the surface. In addition, in 2012 a jet was found to appear during its subsequent perihelion passage as witnessed during an observation carried out on 26th March 2012 using the PRL telescope at Mt. Abu. This confirms recent activity of Comet 49P/Arend-Rigaux due to the volatile subsurface materials exposed after several passages close to the Sun. Our result confirms the subsurface ices on cometary nuclei and insists for more observations for a better understanding.

### Lately Exposed Amorphous Water Ice on Comet 49P/Arend-Rigaux

Comet 49P/ Arend-Rigaux, thought to be a low activity comet since the 1980′s was found to be active in its recent apparitions. Recent analysis of the data obtained from Spitzer observation of the comet in 2006 compared with laboratory spectra has revealed amorphous water ice on the surface. In addition, in 2012 a jet was found to appear during its subsequent perihelion passage as witnessed during an observation carried out on 26th March 2012 using the PRL telescope at Mt. Abu. This confirms recent activity of Comet 49P/Arend-Rigaux due to the volatile subsurface materials exposed after several passages close to the Sun. Our result confirms the subsurface ices on cometary nuclei and insists for more observations for a better understanding.

### Lately Exposed Amorphous Water Ice on Comet 49P/Arend-Rigaux [Replacement]

Comet 49P/ Arend-Rigaux, thought to be a low activity comet since the 1980′s was found to be active in its recent apparitions. Recent analysis of the data obtained from Spitzer observation of the comet in 2006 compared with laboratory spectra has revealed amorphous water ice on the surface. In addition, in 2012 a jet was found to appear during its subsequent perihelion passage as witnessed during an observation carried out on 26th March 2012 using the PRL telescope at Mt. Abu. This confirms recent activity of Comet 49P/Arend-Rigaux due to the volatile subsurface materials exposed after several passages close to the Sun. Our result confirms the subsurface ices on cometary nuclei and insists for more observations for a better understanding.

### Diffusion-desorption ratio of adsorbed CO and CO$_2$ on water ice

Diffusion of atoms and molecules is a key process for the chemical evolution in the star forming regions of the interstellar medium. Accurate data on the mobility of many important interstellar species is however often not available and this provides a serious limitation for the reliability of models describing the physical and chemical processes in molecular clouds. Here we aim to provide the astrochemical modeling community with reliable data on the ratio between the energy barriers for diffusion and desorption for adsorbed CO and CO$_2$ on water ices. To this end, we use a fully atomistic, off-lattice kinetic Monte Carlo technique to generate dynamical trajectories of CO and CO$_2$ molecules on the surface of crystalline ice at temperatures relevant for the interstellar medium. The diffusion to desorption barrier ratios are determined to be 0.31 for CO and 0.39 for CO$_2$ . These ratios can be directly used to improve the accuracy of current gas-grain chemical models.

### Diffusion-desorption ratio of adsorbed CO and CO$_2$ on water ice [Replacement]

Diffusion of atoms and molecules is a key process for the chemical evolution in the star forming regions of the interstellar medium. Accurate data on the mobility of many important interstellar species is however often not available and this provides a serious limitation for the reliability of models describing the physical and chemical processes in molecular clouds. Here we aim to provide the astrochemical modeling community with reliable data on the ratio between the energy barriers for diffusion and desorption for adsorbed CO and CO$_2$ on water ices. To this end, we use a fully atomistic, off-lattice kinetic Monte Carlo technique to generate dynamical trajectories of CO and CO$_2$ molecules on the surface of crystalline ice at temperatures relevant for the interstellar medium. The diffusion to desorption barrier ratios are determined to be 0.31 for CO and 0.39 for CO$_2$ . These ratios can be directly used to improve the accuracy of current gas-grain chemical models.

### Diffusion-desorption ratio of adsorbed CO and CO$_2$ on water ice [Replacement]

Diffusion of atoms and molecules is a key process for the chemical evolution in the star forming regions of the interstellar medium. Accurate data on the mobility of many important interstellar species is however often not available and this provides a serious limitation for the reliability of models describing the physical and chemical processes in molecular clouds. Here we aim to provide the astrochemical modeling community with reliable data on the ratio between the energy barriers for diffusion and desorption for adsorbed CO and CO$_2$ on water ices. To this end, we use a fully atomistic, off-lattice kinetic Monte Carlo technique to generate dynamical trajectories of CO and CO$_2$ molecules on the surface of crystalline ice at temperatures relevant for the interstellar medium. The diffusion to desorption barrier ratios are determined to be 0.31 for CO and 0.39 for CO$_2$ . These ratios can be directly used to improve the accuracy of current gas-grain chemical models.

### Fragmentation of colliding planetesimals with water content

We investigate the outcome of collisions of Ceres-sized planetesimals composed of a rocky core and a shell of water ice. These collisions are not only relevant for explaining the formation of planetary embryos in early planetary systems, but also provide insight into the formation of asteroid families and possible water transport via colliding small bodies. Earlier studies show characteristic collision velocities exceeding the bodies’ mutual escape velocity which – along with the distribution of the impact angles – cover the collision outcome regimes ‘partial accretion’, ‘erosion’, and ‘hit-and-run’ leading to different expected fragmentation scenarios. Existing collision simulations use bodies composed of strengthless material; we study the distribution of fragments and their water contents considering the full elasto-plastic continuum mechanics equations also including brittle failure and fragmentation.

### The gas-ice chemical interplay during cloud evolution

During the evolution of diffuse clouds to molecular clouds, gas-phase molecules freeze out on surfaces of small dust particles to form ices. On dust surfaces, water is the main constituent of the icy mantle in which a complex chemistry is taking place. We aim to study the formation pathways and the composition of the ices throughout the evolution of diffuse clouds. For this purpose, we use time-dependent rate equations to calculate the molecular abundances in both gas phase and on solid surfaces (onto dust grains). We fully consider the gas-dust interplay by including the details of freeze-out, chemical and thermal desorption, as well as the most important photo-processes on grain surfaces. The difference in binding energies of chemical species on bare and icy surfaces is also incorporated into our equations. Using the numerical code FLASH, we perform a hydrodynamical simulation of a gravitationally bound diffuse cloud and follow its contraction. We find that while the dust grains are still bare, water formation is enhanced by grain surface chemistry which is subsequently released into the gas phase, enriching the molecular medium. The CO molecules, on the other hand, tend to freeze out gradually on bare grains. This causes CO to be well mixed and strongly present within the first ice layer. Once one monolayer of water ice has formed, the binding energy of the grain surface changes significantly and an immediate and strong depletion of gas-phase water and CO molecules occur. While hydrogenation converts solid CO into formaldehyde (H$_2$CO) and methanol (CH$_3$OH), water ice becomes the main constituent of the icy grains. Inside molecular clumps formaldehyde is more abundant than water and methanol in the gas phase owing its presence mainly to chemical desorption.

### The irradiation of water ice by C$^+$ ions in the cosmic environment

We present a first principles molecular dynamics (FPMD) study of the interaction of low energy, positively charged, carbon (C+) projectiles with amorphous solid water clusters at 30 K. Reactions involving the carbon ion at an initial energy of 11 eV and 1.7 eV with 30-molecule clusters have been investigated. Simulations indicate that the neutral isoformyl radical, COH, and carbon monoxide, CO, are the dominant products of these reactions. All these reactions are accompanied by the transfer of a proton from the reacting water molecule to the ice, where it forms a hydronium ion. We find that COH is formed either via a direct, "knock-out", mechanism following the impact of the C+ projectile upon a water molecule or by creation of a COH_2^+ intermediate. The direct mechanism is more prominent at higher energies. CO is generally produced following the dissociation of COH. More frequent production of the formyl radical, HCO, is observed here than in gas phase calculations. A less commonly occurring product is the dihydroxymethyl, CH(OH)_2, radical. Although a minor result, its existence gives an indication of the increasing chemical complexity which is possible in such heterogeneous environments.

### A common column density threshold for scattering at 3.6 mum and water-ice in molecular clouds

Context: Observations of scattered light in the 1-5 $\mu$m range have revealed dust grains in molecular cores with sizes larger than commonly inferred for the diffuse interstellar medium. It is currently unclear whether these grains are grown within the molecular cores or are an ubiquitous component of the interstellar medium. Aims: We investigate whether the large grains necessary for efficient scattering at 1-5 mum are associated with the abundance of water-ice within molecular clouds and cores. Methods: We combined water-ice abundance measurements for sight lines through the Lupus IV molecular cloud complex with measurements of the scattered light at 3.6 mum for the same sight lines. Results: We find that there is a similar threshold for the cores in emission in scattered light at 3.6 mum (tau_9.7=0.15pm0.05, A_K=0.4pm0.2 as water-ice (tau_9.7=0.11pm0.01, A_K=0.19pm0.04) and that the scattering efficiency increases as the relative water-ice abundance increases. The ice layer increases the average grain size, which again strongly increases the albedo. Conclusions: The higher scattering efficiency is partly due to layering of ice on the dust grains. Although the layer can be relatively thin it can enhance the scattering substantially.

### Photometric and spectroscopic evidence for a dense ring system around Centaur Chariklo

In this work we aim to study if the variability in the absolute magnitude of Chariklo and the temporal variation of the spectral ice feature, even its disappearance in 2007, can be explained by an icy ring system whose aspect angle changes with time. We modeled the light reflected by a system as the one described above to explain the variations on the absolute magnitude of Chariklo and its rings. Using X-Shooter at VLT we obtained a new reflectance spectra, here we compared this new set of data with the ones available in the literature. We showed how the water ice feature is visible in 2013 in accordance with the ring configuration, which had an opening angle of nearly 34$^o$ in 2013. Finally we also used models of the scattering of light to fit the visible and near-infrared spectra showing different characteristic to obtain information on the composition of Chariklo and its rings. {We showed that past absolute photometry of Chariklo from the literature and new photometric data that we obtained in 2013 can be explained by a ring of particles whose opening angle changes as a function of time. We used the two possible pole solutions for the ring system and found that only one of them, $\alpha$=151.30$\pm0.5$, $\delta=41.48\pm0.2$ $^o$ ($\lambda=137.9\pm0.5$, $\beta=27.7\pm0.2$ $^o$) provides the right variation of the aspect angle with time to explain the photometry, whereas the other possible pole solution fails to explain the photometry. From spectral modeling, using the result on the pole solution, we derived the composition of Chariklo surface and of that of the rings. Chariklo surface is composed by nearly 60% of amorphous carbon, 30% of silicates and 10\% of organics, no water ice was found on the surface. Whereas the ring contains 20% of water ice, 40-70% of silicates and 10-30% of tholins and small quantities of amorphous carbon.

### Photometric and spectroscopic evidence for a dense ring system around Centaur Chariklo [Replacement]

In this work we aim to study if the variability in the absolute magnitude of Chariklo and the temporal variation of the spectral ice feature, even its disappearance in 2007, can be explained by an icy ring system whose aspect angle changes with time. We modeled the light reflected by a system as the one described above to explain the variations on the absolute magnitude of Chariklo and its rings. Using X-Shooter at VLT we obtained a new reflectance spectra, here we compared this new set of data with the ones available in the literature. We showed how the water ice feature is visible in 2013 in accordance with the ring configuration, which had an opening angle of nearly 34$^o$ in 2013. Finally we also used models of the scattering of light to fit the visible and near-infrared spectra showing different characteristic to obtain information on the composition of Chariklo and its rings. {We showed that past absolute photometry of Chariklo from the literature and new photometric data that we obtained in 2013 can be explained by a ring of particles whose opening angle changes as a function of time. We used the two possible pole solutions for the ring system and found that only one of them, $\alpha$=151.30$\pm0.5$, $\delta=41.48\pm0.2$ $^o$ ($\lambda=137.9\pm0.5$, $\beta=27.7\pm0.2$ $^o$) provides the right variation of the aspect angle with time to explain the photometry, whereas the other possible pole solution fails to explain the photometry. From spectral modeling, using the result on the pole solution, we derived the composition of Chariklo surface and of that of the rings. Chariklo surface is composed by nearly 60% of amorphous carbon, 30% of silicates and 10\% of organics, no water ice was found on the surface. Whereas the ring contains 20% of water ice, 40-70% of silicates and 10-30% of tholins and small quantities of amorphous carbon.

### Interannual observations and quantification of summertime H2O ice deposition on the Martian CO2 ice south polar cap

The spectral signature of water ice was observed on Martian south polar cap in 2004 by the Observatoire pour l’Mineralogie, l’Eau les Glaces et l’Activite (OMEGA) (Bibring et al., 2004). Three years later, the OMEGA instrument was used to discover water ice deposited during southern summer on the polar cap (Langevin et al., 2007). However, temporal and spatial variations of these water ice signatures have remained unexplored, and the origins of these water deposits remains an important scientific question. To investigate this question, we have used observations from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) instrument on the Mars Reconnaissance Orbiter (MRO) spacecraft of the southern cap during austral summer over four Martian years to search for variations in the amount of water ice. We report below that for each year we have observed the cap, the magnitude of the H2O ice signature on the southern cap has risen steadily throughout summer, particularly on the west end of the cap. The spatial extent of deposition is in disagreement with the current best simulations of deposition of water ice on the south polar cap (Montmessin et al., 2007). This increase in water ice signatures is most likely caused by deposition of atmospheric H2O ice and a set of unusual conditions makes the quantification of this transport flux using CRISM close to ideal. We calculate a ‘minimum apparent’ amount of deposition corresponding to a thin H2O ice layer of 0.2mm (with 70 percent porosity). This amount of H2O ice deposition is 0.6-6 percent of the total Martian atmospheric water budget. We compare our ‘minimal apparent’ quantification with previous estimates. This deposition process may also have implications for the formation and stability of the southern CO2 ice cap, and therefore play a significant role in the climate budget of modern day Mars.

### Interactions of adsorbed CO$_2$ on water ice at low temperatures

We present a computational study into the adsorption properties of CO$_2$ on amorphous and crystalline water surfaces under astrophysically relevant conditions. Water and carbon dioxide are two of the most dominant species in the icy mantles of interstellar dust grains and a thorough understanding of their solid phase interactions at low temperatures is crucial for understanding the structural evolution of the ices due to thermal segregation. In this paper, a new H$_2$O-CO$_2$ interaction potential is proposed and used to model the ballistic deposition of CO$_2$ layers on water ice surfaces, and to study the individual binding sites at low coverages. Contrary to recent experimental results, we do not observe CO$_2$ island formation on any type of water substrate. Additionally, density functional theory calculations are performed to assess the importance of induced electrostatic interactions.

### Water Ice and Dust in the Innermost Coma of Comet 103P/Hartley 2

On November 4th, 2010, the Deep Impact eXtended Investigation (DIXI) successfully encountered comet 103P/Hartley 2, when it was at a heliocentric distance of 1.06 AU. Spatially resolved near-IR spectra of comet Hartley 2 were acquired in the 1.05-4.83 micron wavelength range using the HRI-IR spectrometer. We present spectral maps of the inner ~10 kilometers of the coma collected 7 minutes and 23 minutes after closest approach. The extracted reflectance spectra include well-defined absorption bands near 1.5, 2.0, and 3.0 micron consistent in position, bandwidth, and shape with the presence of water ice grains. Using Hapke’s radiative transfer model, we characterize the type of mixing (areal vs. intimate), relative abundance, grain size, and spatial distribution of water ice and refractories. Our modeling suggests that the dust, which dominates the innermost coma of Hartley 2 and is at a temperature of 300K, is thermally and physically decoupled from the fine-grained water ice particles, which are on the order of 1 micron in size. The strong correlation between the water ice, dust, and CO2 spatial distribution supports the concept that CO2 gas drags the water ice and dust grains from the nucleus. Once in the coma, the water ice begins subliming while the dust is in a constant outflow. The derived water ice scale-length is compatible with the lifetimes expected for 1-micron pure water ice grains at 1 AU, if velocities are near 0.5 m/s. Such velocities, about three order of magnitudes lower than the expansion velocities expected for isolated 1-micron water ice particles [Hanner, 1981; Whipple, 1951], suggest that the observed water ice grains are likely aggregates.

### Cold Water Vapor in the Barnard 5 Molecular Cloud

After more than 30 years of investigations, the nature of gas-grain interactions at low temperatures remains an unresolved issue in astrochemistry. Water ice is the dominant ice found in cold molecular clouds, however, there is only one region where cold (~10 K) water vapor has been detected – L1544. This study aims to shed light on ice desorption mechanisms under cold cloud conditions by expanding the sample. The clumpy distribution of methanol in dark clouds testifies to transient desorption processes at work — likely to also disrupt water ice mantles. Therefore, the Herschel HIFI instrument was used to search for cold water in a small sample of prominent methanol emission peaks. We report detections of the ground-state transition of o-H2O (J = 1_10 – 1_01) at 556.9360 GHz toward two positions in the cold molecular cloud Barnard 5. The relative abundances of methanol and water gas support a desorption mechanism which disrupts the outer ice mantle layers, rather than causing complete mantle removal.

### Thermal desorption of circumstellar and cometary ice analogs

Thermal annealing of interstellar ices takes place in several stages of star formation. Knowledge of this process comes from a combination of astronomical observations and laboratory simulations under astrophysically relevant conditions. For the first time we present the results of temperature programmed desorption (TPD) experiments with pre-cometary ice analogs composed of up to five molecular components: H2 O, CO, CO2, CH3 OH, and NH3 . The experiments were performed with an ultra-high vacuum chamber. A gas line with a novel design allows the controlled preparation of mixtures with up to five molecular components. Volatiles desorbing to the gas phase were monitored using a quadrupole mass spectrometer, while changes in the ice structure and composition were studied by means of infrared spectroscopy. The TPD curves of water ice containing CO, CO2, CH3 OH, and NH3 present desorption peaks at temperatures near those observed in pure ice experiments, volcano desorption peaks after water ice crystallization, and co-desorption peaks with water. Desorption peaks of CH3 OH and NH3 at temperatures similar to the pure ices takes place when their abundance relative to water is above 3%, approx., in the ice matrix. We found that CO, CO2, and NH3 also present co-desorption peaks with CH3 OH, which cannot be reproduced in experiments with binary water-rich ice mixtures. These are extensively used in the study of thermal desorption of interstellar ices. These results reproduce the heating of circumstellar ices in hot cores and can be also applied to the late thermal evo- lution of comets. In particular, TPD curves represent a benchmark for the analysis of the measurements that mass spectrometers on board the ESA-Rosetta cometary mission will perform on the coma of comet 67P/Churyumov-Gerasimenko, which will be active before the arrival of Rosetta according to our predictions.

### Disintegration of Comet C/2012 S1 (ISON) Shortly Before Perihelion: Evidence from Independent Data Sets

As an Oort Cloud object with a record small perihelion distance of 2.7 Rsun and discovered more than a year before its encounter with the Sun, comet C/2012 S1 is a subject of considerable scientific interest. Its activity along the orbit’s inbound leg evolved through a series of cycles. Two remarkable events preserved in SOHO’s and/or STEREO’s near-perihelion images of its tail were an early massive production of gravel at heliocentric distances of up to ~100 AU(!), evidently by the annealing of amorphous water ice on and near the nucleus’ surface; and, about a week before perihelion, a rapid series of powerful explosions, from the comet’s interior, of water with dust at extremely high rates, causing precipitous fragmentation of the nucleus, shattering it into a vast number of sublimating boulders, and ending up, a few days later, with a major, sudden drop in gas emission. The disintegration of the comet was completed by about 3.5 hours before perihelion, at a heliocentric distance of 5.2 Rsun, when C/2012 S1 ceased to exist as an active comet. The orbital motion in this period of time was subjected to progressively increasing outgassing-driven perturbations. A comprehensive orbital analysis results in successfully fitting the comet’s observed motion from 2011 to ~7 hours before perihelion.

### Disintegration of Comet C/2012 S1 (ISON) Shortly Before Perihelion: Evidence from Independent Data Sets [Replacement]

As an Oort Cloud object with a record small perihelion distance of 2.7 Rsun and discovered more than a year before its encounter with the Sun, comet C/2012 S1 is a subject of considerable scientific interest. Its activity along the orbit’s inbound leg evolved through a series of cycles. Two remarkable events preserved in SOHO’s and/or STEREO’s near-perihelion images of its tail were an early massive production of gravel at heliocentric distances of up to ~100 AU, evidently by the annealing of amorphous water ice on and near the nucleus’ surface; and, about a week before perihelion, a rapid series of powerful explosions, from the comet’s interior, of water with dust at extremely high rates, causing precipitous fragmentation of the nucleus, shattering it into a vast number of sublimating boulders, and ending up, a few days later, with a major, sudden drop in gas emission. The disintegration of the comet was completed by about 3.5 hours before perihelion, at a heliocentric distance of 5.2 Rsun, when C/2012 S1 ceased to exist as an active comet. The orbital motion in this period of time was subjected to progressively increasing outgassing-driven perturbations. A comprehensive orbital analysis results in successfully fitting the comet’s observed motion from 2011 to ~7 hours before perihelion.

### Disintegration of Comet C/2012 S1 (ISON) Shortly Before Perihelion: Evidence from Independent Data Sets [Replacement]

As an Oort Cloud object with a record small perihelion distance of 2.7 Rsun and discovered more than a year before its encounter with the Sun, comet C/2012 S1 is a subject of considerable scientific interest. Its activity along the orbit’s inbound leg evolved through a series of cycles. Two remarkable events preserved in SOHO’s and/or STEREO’s near-perihelion images of its tail were an early massive production of gravel at heliocentric distances of up to ~100 AU, evidently by the annealing of amorphous water ice on and near the nucleus’ surface; and, about a week before perihelion, a rapid series of powerful explosions, from the comet’s interior, of water with dust at extremely high rates, causing precipitous fragmentation of the nucleus, shattering it into a vast number of sublimating boulders, and ending up, a few days later, with a major, sudden drop in gas emission. The disintegration of the comet was completed by about 3.5 hours before perihelion, at a heliocentric distance of 5.2 Rsun, when C/2012 S1 ceased to exist as an active comet. The orbital motion in this period of time was subjected to progressively increasing outgassing-driven perturbations. A comprehensive orbital analysis results in successfully fitting the comet’s observed motion from 2011 to ~7 hours before perihelion.

### Disintegration of Comet C/2012 S1 (ISON) Shortly Before Perihelion: Evidence from Independent Data Sets [Replacement]

As an Oort Cloud object with a record small perihelion distance of 2.7 Rsun and discovered more than a year before its encounter with the Sun, comet C/2012 S1 is a subject of considerable scientific interest. Its activity along the orbit’s inbound leg evolved through a series of cycles. Two remarkable events preserved in SOHO’s and/or STEREO’s near-perihelion images of its tail were an early massive production of gravel at heliocentric distances of up to ~100 AU, evidently by the annealing of amorphous water ice on and near the nucleus’ surface; and, about a week before perihelion, a rapid series of powerful explosions, from the comet’s interior, of water with dust at extremely high rates, causing precipitous fragmentation of the nucleus, shattering it into a vast number of sublimating boulders, and ending up, a few days later, with a major, sudden drop in gas emission. The disintegration of the comet was completed by about 3.5 hours before perihelion, at a heliocentric distance of 5.2 Rsun, when C/2012 S1 ceased to exist as an active comet. The orbital motion in this period of time was subjected to progressively increasing outgassing-driven perturbations. A comprehensive orbital analysis results in successfully fitting the comet’s observed motion from 2011 to ~7 hours before perihelion.

### Disintegration of Comet C/2012 S1 (ISON) Shortly Before Perihelion: Evidence from Independent Data Sets [Replacement]

As an Oort Cloud object with a record small perihelion distance of 2.7 Rsun and discovered more than a year before its encounter with the Sun, comet C/2012 S1 is a subject of considerable scientific interest. Its activity along the orbit’s inbound leg evolved through a series of cycles. Two remarkable events preserved in SOHO’s and/or STEREO’s near-perihelion images of its tail were an early massive production of gravel at heliocentric distances of up to ~100 AU, evidently by the annealing of amorphous water ice on and near the nucleus’ surface; and, about a week before perihelion, a rapid series of powerful explosions, from the comet’s interior, of water with dust at extremely high rates, causing precipitous fragmentation of the nucleus, shattering it into a vast number of sublimating boulders, and ending up, a few days later, with a major, sudden drop in gas emission. The disintegration of the comet was completed by about 3.5 hours before perihelion, at a heliocentric distance of 5.2 Rsun, when C/2012 S1 ceased to exist as an active comet. The orbital motion in this period of time was subjected to progressively increasing outgassing-driven perturbations. A comprehensive orbital analysis results in successfully fitting the comet’s observed motion from 2011 to ~7 hours before perihelion.

### The Effect of Planets Beyond the Ice Line on the Accretion of Volatiles by Habitable-Zone Rocky Planets

Models of planet formation have shown that giant planets have a large impact on the number, masses and orbits of terrestrial planets that form. In addition, they play an important role in delivering volatiles from material that formed exterior to the snow-line (the region in the disk beyond which water ice can condense) to the inner region of the disk where terrestrial planets can maintain liquid water on their surfaces. We present simulations of the late stages of terrestrial planet formation from a disk of protoplanets around a solar-type star, and we include a massive planet (from 1 Earth mass to 1 Jupiter mass) in Jupiter’s orbit at ~5.2 AU in all but one set of simulations. Two initial disk models are examined with the same mass distribution and total initial water content, but with different distributions of water content. We compare the accretion rates and final water mass fraction of the planets that form. Remarkably, all of the planets that formed in our simulations without giant planets were water-rich, showing that giant planet companions are not required to deliver volatiles to terrestrial planets in the habitable zone. In contrast, an outer planet at least several times the mass of Earth may be needed to clear distant regions from debris truncating the epoch of frequent large impacts. Observations of exoplanets from radial velocity surveys suggest that outer Jupiter-like planets may be scarce, therefore the results presented here suggest the number of habitable planets that reside in our galaxy may be more than previously thought.

### Water and methanol in low-mass protostellar outflows: gas-phase synthesis, ice sputtering and destruction

Water in outflows from protostars originates either as a result of gas-phase synthesis from atomic oxygen at T > 200 K, or from sputtered ice mantles containing water ice. We aim to quantify the contribution of the two mechanisms that lead to water in outflows, by comparing observations of gas-phase water to methanol (a grain surface product) towards three low-mass protostars in NGC1333. In doing so, we also quantify the amount of methanol destroyed in outflows. To do this, we make use of JCMT and Herschel-HIFI data of H2O, CH3OH and CO emission lines and compare them to RADEX non-LTE excitation simulations. We find up to one order of magnitude decrease in the column density ratio of CH3OH over H2O as the velocity increases in the line wings up to ~15 km/s. An independent decrease in X(CH3OH) with respect to CO of up to one order of magnitude is also found in these objects. We conclude that gas-phase formation of H2O must be active at high velocities (above 10 km/s, relative to the source velocity) to re-form the water destroyed during sputtering. In addition, the transition from sputtered water at low velocities to formed water at high velocities must be gradual. We place an upper limit of two orders of magnitude on the destruction of methanol by sputtering effects.

### Multi-Wavelength Observations of Comet C/2011 L4 (Pan-Starrs)

Dynamically new comet C/2011 L4 (PanSTARRS) is one of the brightest comets since the great comet C/1995 O1 (Hale-Bopp). Here, we present our multi-wavelength observations of C/2011 L4 during its in-bound passage to the inner Solar system. A strong absorption band of water ice at 2.0 $\mu$m was detected in the near infrared spectra, taken with the 8-m Gemini-North and 3-m IRTF telescopes. The companion 1.5 $\mu$m band of water ice, however, was not observed. Spectral modeling show that the absence of the 1.5 $\mu$m feature can be explained by the presence of sub-micron-sized fine ice grains. No gas lines (i.e. CN, HCN or CO) were observed pre-perihelion either in the optical or in the sub-millimeter. 3-$\sigma$ upper limits to the CN and CO production rates were derived. The comet exhibited a very strong continuum in the optical and its slope seemed to become redder as the comet approached the Sun. Our observations suggest that C/2011 L4 is an unusually dust-rich comet with a dust-to-gas mass ratio $>$ 4.

### The Phases of Water Ice in the Solar Nebula

Understanding the phases of water ice that were present in the solar nebula has implications for understanding cometary and planetary compositions as well as internal evolution of these bodies. Here we show that amorphous ice formed more readily than previously recognized, with formation at temperatures <70 K being possible under protoplanetary disk conditions. We further argue that photodesorption and freeze-out of water molecules near the surface layers of the solar nebula would have provided the conditions needed for amorphous ice to form. This processing would be a natural consequence of ice dynamics, and would allow for the trapping of noble gases and other volatiles in water ice in the outer solar nebula.

### Quantum tunneling of oxygen atoms on very cold surfaces [Cross-Listing]

Any evolving system can change of state via thermal mechanisms (hopping a barrier) or via quantum tunneling. Most of the time, efficient classical mechanisms dominate at high temperatures. This is why an increase of the temperature can initiate the chemistry. We present here an experimental investigation of O-atom diffusion and reactivity on water ice. We explore the 6-25 K temperature range at sub-monolayer surface coverages. We derive the diffusion temperature law and observe the transition from quantum to classical diffusion. Despite of the high mass of O, quantum tunneling is efficient even at 6 K. As a consequence, the solid-state astrochemistry of cold regions should be reconsidered and should include the possibility of forming larger organic molecules than previously expected.

### CRISM south polar mapping: First Mars year of observations

We report on mapping of the south polar region of Mars using data from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) instrument. Our observations have led to the following discoveries: 1. Water ice is present in the form of pole-circling clouds originating from the circum-Hellas region, beginning prior to Ls=162 and diminishing markedly at Ls=200-204. 2. It has previously been inferred by temperature measurements(Titus et al., 2003) and CO2-H2O mixture spectral models (Langevin et al., 2007) that surface water ice was present in the Cryptic Region in the final stages of sublimation. The high resolution of CRISM has revealed regions where only water ice is present (not a CO2-H2O ice mixture). This water ice disappears completely by Ls=252 and may be the source of water vapor observed by CRISM in southern latitudes between Ls=240-260 (Smith, et al., this issue). 3. We have estimated surface CO2 ice grain size distributions for the South Pole Residual Cap (SPRC) and the seasonal CO2 ice cap that covers it throughout summer spring and summer. Our analysis suggests that grain sizes peak at Ls=191-199 with an apparent grain size of ~7 +/-1 cm. By the end of the summer period our analysis demonstrates minimum apparent grain sizes of ~5 +/-1 mm predominate in the SPRC. 4. Fine grained CO2 ice condenses from Ls=0-40, and extends symmetrically away from the geographic pole, extending beyond 80 deg S by Ls=4-10. No evidence for unusual CO2 depositional processes in the Cryptic Region is observed up to Ls=16.

### Louth Crater: Evolution of a layered water ice mound

We report on observations made of the ~36km diameter crater, Louth, in the north polar region of Mars (at 70{\deg}N, 103.2{\deg}E). High-resolution imagery from the instruments on the Mars Reconnaissance Orbiter (MRO) spacecraft has been used to map a 15km diameter water ice deposit in the center of the crater. The water ice mound has surface features that include roughened ice textures and layering similar to that found in the North Polar Layered Deposits. Features we interpret as sastrugi and sand dunes show consistent wind patterns within Louth over recent time. CRISM spectra of the ice mound were modeled to derive quantitative estimates of water ice and contaminant abundance, and associated ice grain size information. These morphologic and spectral results are used to propose a stratigraphy for this deposit and adjoining sand dunes. Our results suggest the edge of the water ice mound is currently in retreat.

### Rotationally resolved spectroscopy of (20000) Varuna in the near-infrared

Models of the escape and retention of volatiles by minor icy objects exclude any presence of volatile ices on the surface of TNOs smaller than ~1000km in diameter at the typical temperature in this region of the solar system, whereas the same models show that water ice is stable on the surface of objects over a wide range of diameters. Collisions and cometary activity have been used to explain the process of surface refreshing of TNOs and Centaurs. These processes can produce surface heterogeneity that can be studied by collecting information at different rotational phases. The aims of this work are to study the surface composition of (20000)Varuna, a TNO with a diameter ~650km and to search for indications of rotational variability. We observed Varuna during two consecutive nights in January 2011 with NICS@TNG obtaining a set of spectra covering the whole rotation period of Varuna. After studying the spectra corresponding to different rotational phases, we did not find any indication of surface variability. In all the spectra, we detect an absorption at 2{\mu}m, suggesting the presence of water ice on the surface. We do not detect any other volatiles on the surface, although the S/N is not high enough to discard their presence. Based on scattering models, we present two possible compositions compatible with our set of data and discuss their implications in the frame of the collisional history of the Kuiper Belt. We find that the most probable composition for the surface of Varuna is a mixture of amorphous silicates, complex organics, and water ice. This composition is compatible with all the materials being primordial. However, our data can also be fitted by models containing up to a 10% of methane ice. For an object with the characteristics of Varuna, this volatile could not be primordial, so an event, such as an energetic impact, would be needed to explain its presence on the surface.

### Survival of water ice in Jupiter Trojans

Jupiter Trojans appear to be a key population of small bodies to study and test the models of the Solar System formation and evolution. Because understanding the evolution of Trojans can bring strong and unique constraints on the origins of our planetary system, a significant observational effort has been undertaken to unveil their physical characteristics. The data gathered so far are consistent with Trojans having volatile-rich interiors (possibly water ice) and volatile-poor surfaces (fine grained silicates). Since water ice is not thermodynamically stable against sublimation at the surface of an object located at ~5 AU, such layering seems consistent with past outgassing. In this work, we study the thermal history of Trojans after the formation of a dust mantle by possible past outgassing, so as to constrain the depth at which water ice could be stable. We find that it could have survived 100 m below the surface, even if Trojans orbited close to the Sun for ~10,000 years, as suggested by the most recent dynamical models. Water ice should be found ~10 m below the surface in most cases, and below 10 cm in the polar regions in some cases.

### Dynamics of CO in Amorphous Water Ice Environments

The long-timescale behavior of adsorbed carbon monoxide on the surface of amorphous water ice is studied under dense cloud conditions by means of off-lattice, on-the-fly, kinetic Monte Carlo simula- tions. It is found that the CO mobility is strongly influenced by the morphology of the ice substrate. Nanopores on the surface provide strong binding sites which can effectively immobilize the adsorbates at low coverage. As the coverage increases, these strong binding sites are gradually occupied leav- ing a number of admolecules with the ability to diffuse over the surface. Binding energies, and the energy barrier for diffusion are extracted for various coverages. Additionally, the mobility of CO is determined from isothermal desorption experiments. Reasonable agreement on the diffusivity of CO is found with the simulations. Analysis of the 2152 cm$^{-1}$, polar CO band supports the computational findings that the pores in the water ice provide the strongest binding sites and dominate diffusion at low temperatures.

### Dynamics of CO in Amorphous Water Ice Environments [Replacement]

The long-timescale behavior of adsorbed carbon monoxide on the surface of amorphous water ice is studied under dense cloud conditions by means of off-lattice, on-the-fly, kinetic Monte Carlo simula- tions. It is found that the CO mobility is strongly influenced by the morphology of the ice substrate. Nanopores on the surface provide strong binding sites which can effectively immobilize the adsorbates at low coverage. As the coverage increases, these strong binding sites are gradually occupied leav- ing a number of admolecules with the ability to diffuse over the surface. Binding energies, and the energy barrier for diffusion are extracted for various coverages. Additionally, the mobility of CO is determined from isothermal desorption experiments. Reasonable agreement on the diffusivity of CO is found with the simulations. Analysis of the 2152 cm$^{-1}$, polar CO band supports the computational findings that the pores in the water ice provide the strongest binding sites and dominate diffusion at low temperatures.

### Water in Protoplanetary Disks: Deuteration and Turbulent Mixing

We investigate water and deuterated water chemistry in turbulent protoplanetary disks. Chemical rate equations are solved with the diffusion term, mimicking turbulent mixing in vertical direction. Water near the midplane is transported to the disk atmosphere by turbulence and destroyed by photoreactions to produce atomic oxygen, while the atomic oxygen is transported to the midplane and reforms water and/or other molecules. We find that this cycle significantly decreases column densities of water ice at r < 30 AU, where dust temperatures are too high to reform water ice effectively. The radial extent of such region depends on the desorption energy of atomic hydrogen. Our model indicates that water ice could be deficient even outside the sublimation radius. Outside this radius, the cycle decreases the D/H ratio of water ice from 2×10^-2, which is set by the collapsing core model, to 10^-4-10^-2 in 10^6 yr, without significantly decreasing the water ice column density. The resultant D/H ratios depend on the strength of mixing and the radial distance from the central star. Our finding suggests that the D/H ratio of cometary water (10^-3-10^-4) could be established (i.e. cometary water could be formed) in the solar nebula, even if the D/H ratio of water ice delivered to the disk was very high (10^-2).

### Outgassing Behavior of C/2012 S1 (ISON) From September 2011 to June 2013

We report photometric observations for comet C/2012 S1 (ISON) obtained during the time period immediately after discovery (r=6.28 AU) until it moved into solar conjunction in mid-2013 June using the UH2.2m, and Gemini North 8-m telescopes on Mauna Kea, the Lowell 1.8m in Flagstaff, the Calar Alto 1.2m telescope in Spain, the VYSOS-5 telescopes on Mauna Loa Hawaii and data from the CARA network. Additional pre-discovery data from the Pan STARRS1 survey extends the light curve back to 2011 September 30 (r=9.4 AU). The images showed a similar tail morphology due to small micron sized particles throughout 2013. Observations at sub-mm wavelengths using the JCMT on 15 nights between 2013 March 9 (r=4.52 AU) and June 16 (r=3.35 AU) were used to search for CO and HCN rotation lines. No gas was detected, with upper limits for CO ranging between (3.5-4.5)E27 molec/s. Combined with published water production rate estimates we have generated ice sublimation models consistent with the photometric light curve. The inbound light curve is likely controlled by sublimation of CO2. At these distances water is not a strong contributor to the outgassing. We also infer that there was a long slow outburst of activity beginning in late 2011 peaking in mid-2013 January (r~5 AU) at which point the activity decreased again through 2013 June. We suggest that this outburst was driven by CO injecting large water ice grains into the coma. Observations as the comet came out of solar conjunction seem to confi?rm our models.

### Outgassing Behavior of C/2012 S1 (ISON) From September 2011 to June 2013 [Replacement]

We report photometric observations for comet C/2012 S1 (ISON) obtained during the time period immediately after discovery (r=6.28 AU) until it moved into solar conjunction in mid-2013 June using the UH2.2m, and Gemini North 8-m telescopes on Mauna Kea, the Lowell 1.8m in Flagstaff, the Calar Alto 1.2m telescope in Spain, the VYSOS-5 telescopes on Mauna Loa Hawaii and data from the CARA network. Additional pre-discovery data from the Pan STARRS1 survey extends the light curve back to 2011 September 30 (r=9.4 AU). The images showed a similar tail morphology due to small micron sized particles throughout 2013. Observations at sub-mm wavelengths using the JCMT on 15 nights between 2013 March 9 (r=4.52 AU) and June 16 (r=3.35 AU) were used to search for CO and HCN rotation lines. No gas was detected, with upper limits for CO ranging between (3.5-4.5)E27 molec/s. Combined with published water production rate estimates we have generated ice sublimation models consistent with the photometric light curve. The inbound light curve is likely controlled by sublimation of CO2. At these distances water is not a strong contributor to the outgassing. We also infer that there was a long slow outburst of activity beginning in late 2011 peaking in mid-2013 January (r~5 AU) at which point the activity decreased again through 2013 June. We suggest that this outburst was driven by CO injecting large water ice grains into the coma. Observations as the comet came out of solar conjunction seem to confi?rm our models.

### On the chemical composition of Titan's dry lakebed evaporites

Titan, the main satellite of Saturn, has an active cycle of methane in its troposphere. Among other evidence for a mechanism of evaporation at work on the ground, dry lakebeds have been discovered. Recent Cassini infrared observations of these empty lakes have revealed a surface composition poor in water ice compared to that of the surrounding terrains — suggesting the existence of organic evaporites deposits. The chemical composition of these possible evaporites is unknown. In this paper, we study evaporite composition using a model that treats both organic solids dissolution and solvent evaporation. Our results suggest the possibility of large abundances of butane and acetylene in the lake evaporites. However, due to uncertainties of the employed theory, these determinations have to be confirmed by laboratory experiments.

### A Trend Between Cold Debris Disk Temperature and Stellar Type: Implications for the Formation and Evolution of Wide-Orbit Planets

Cold debris disks trace the limits of planet formation or migration in the outer regions of planetary systems, and thus have the potential to answer many of the outstanding questions in wide-orbit planet formation and evolution. We characterized the infrared excess spectral energy distributions of 174 cold debris disks around 546 main-sequence stars observed by both Spitzer IRS and MIPS. We found a trend between the temperature of the inner edges of cold debris disks and the stellar type of the stars they orbit. This argues against the importance of strictly temperature-dependent processes (e.g. non-water ice lines) in setting the dimensions of cold debris disks. Also, we found no evidence that delayed stirring causes the trend. The trend may result from outward planet migration that traces the extent of the primordial protoplanetary disk, or it may result from planet formation that halts at an orbital radius limited by the efficiency of core accretion.

### Climatology of the Martian Polar Regions: Three Mars Years of CRISM/MARCI Observations of Atmospheric Clouds and Dust

We present the synthesis of CRISM EPF and MARCI data to examine the evolution of atmospheric water ice and dust opacity at both poles for MY 28-30.

### Signpost of Multiple Planets in Debris Disks

We review the nearby debris disk structures revealed by multi-wavelength images from Spitzer and Herschel, and complemented with detailed spectral energy distribution modeling. Similar to the definition of habitable zones around stars, debris disk structures should be identified and characterized in terms of dust temperatures rather than physical distances so that the heating power of different spectral type of stars is taken into account and common features in disks can be discussed and compared directly. Common features, such as warm (~150 K) dust belts near the water-ice line and cold (~50 K) Kuiper-belt analogs, give rise to our emerging understanding of the levels of order in debris disk structures and illuminate various processes about the formation and evolution of exoplanetary systems. In light of the disk structures in the debris disk twins (Vega and Fomalhaut), and the current limits on the masses of planetary objects, we suggest that the large gap between the warm and cold dust belts is the best signpost for multiple (low-mass) planets beyond the water-ice line.

### Modeling the HD32297 Debris Disk with Far-IR Herschel Data

HD32297 is a young A-star (~30 Myr) 112 pc away with a bright edge-on debris disk that has been resolved in scattered light. We observed the HD32297 debris disk in the far-infrared and sub-millimeter with the Herschel Space Observatory PACS and SPIRE instruments, populating the spectral energy distribution (SED) from 63 to 500{\mu}m. We aimed to determine the composition of dust grains in the HD32297 disk through SED modeling, using geometrical constraints from the resolved imaging to break degeneracies inherent in SED modeling. We found the best fitting SED model has 2 components: an outer ring centered around 110 AU, seen in the scattered light images, and an inner disk near the habitable zone of the star. The outer disk appears to be composed of grains > 2{\mu}m consisting of silicates, carbonaceous material, and water ice with an abundance ratio of 1:2:3 respectively and 90% porosity. These grains appear consistent with cometary grains, implying the underlying planetesimal population is dominated by comet-like bodies. We also discuss the 3.7{\sigma} detection of [C II] emission at 158{\mu}m with the Herschel PACS Spectrometer, making HD32297 one of only a handful of debris disks with circumstellar gas detected.

### The Effect of Host Star Spectral Energy Distribution and Ice-Albedo Feedback on the Climate of Extrasolar Planets

Planetary climate can be affected by the interaction of the host star spectral energy distribution with the wavelength-dependent reflectivity of ice and snow. Here we explore this effect using a one dimensional (1-D), line-by-line, radiative-transfer model to calculate broadband planetary albedos as input to a seasonally varying, 1-D energy-balance climate model. A three-dimensional general circulation model is also used to explore the atmosphere’s response to changes in incoming stellar radiation, or instellation, and surface albedo. Using this hierarchy of models we simulate planets covered by ocean, land, and water ice of varying grain size, with incident radiation from stars of different spectral types. Terrestrial planets orbiting stars with higher near-UV radiation exhibit a stronger ice-albedo feedback. We find that ice-covered conditions occur on an F-dwarf planet with only a 2% reduction in instellation relative to the present instellation on Earth, assuming fixed CO2 (present atmospheric level on Earth). A similar planet orbiting the Sun at an equivalent flux distance requires an 8% reduction in instellation, while a planet orbiting an M-dwarf star requires an additional 19% reduction in instellation to become ice-covered, equivalent to 73% of the modern solar constant. The surface ice-albedo feedback effect becomes less important at the outer edge of the habitable zone, where atmospheric CO2 can be expected to be high in order to maintain clement conditions for surface liquid water. We show that 3-10 bars of CO2 will entirely mask the climatic effect of ice and snow, leaving the outer limits of the habitable zone unaffected by the spectral dependence of water ice and snow albedo. However, less CO2 is needed to maintain open water for a planet orbiting an M-dwarf star, than would be the case for hotter main-sequence stars.

### Volatile Transport inside Super-Earths by Entrapment in the Water Ice Matrix

Whether volatiles can be entrapped in a background matrix composing planetary envelopes and be dragged via convection to the surface is a key question in understanding atmospheric fluxes, cycles and composition. In this paper we consider super-Earths with an extensive water mantle (i.e. water planets), and the possibility of entrapment of methane in their extensive water ice envelopes. We adopt the theory developed by van der Waals & Platteeuw (1959) for modelling solid solutions, often used for modelling clathrate hydrates, and modify it in order to estimate the thermodynamic stability field of a new phase, called methane filled ice Ih. We find that in comparison to water ice VII the filled ice Ih structure may be stable not only at the high pressures but also at the high temperatures expected at the core-water mantle transition boundary of water planets.